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strato.eqn @ 3719

Last change on this file since 3719 was 2696, checked in by kanani, 7 years ago
Merge of branch palm4u into trunk
File size: 6.5 KB

Line
1	#EQUATIONS
2
3	{ REGION A. STRATOSPHERIC REACTION LIST}
4
5	{ 1.} O + O2 = O3 : 8.018216E-17 ;
6	{ 2.} O + O3 = 2O2 : 1.575705E-15 ;
7	{ 3.} O1D + N2 = O + N2 : 2.838868E-11 ;
8	{ 4.} O1D + O2 = O + O2 : 4.276308E-11 ;
9	{ 5.} O1D + O3 = 2O2 : 1.200000E-10 ;
10	{ 6.} H2O + O1D = 2OH : 2.200000E-10 ;
11	{ 7.} H2 + O1D = OH + H : 1.000000E-10 ;
12	{ 8.} CH4 + O1D = CH2O + H2 : 7.500000E-12 ;
13	{ 9.} CH4 + O1D = CH3 + OH : 1.425000E-10 ;
14	{10.} H + O2 = HO2 : 6.353884E-15 ;
15	{11.} H + O3 = OH + O2 : 1.998353E-11 ;
16	{12.} H2 + OH = H2O + H : 1.388923E-15 ;
17	{13.} OH + O3 = HO2 + O2 : 3.259930E-14 ;
18	{14.} OH + O = O2 + H : 3.616461E-11 ;
19	{15.} OH + OH = H2O + O : 1.554272E-12 ;
20	{16.} HO2 + O = OH + O2 : 6.868940E-11 ;
21	{17.} HO2 + O3 = OH + 2O2 : 1.386665E-15 ;
22	{18.} H + HO2 = 2OH : 7.000000E-11 ;
23	{19.} HO2 + OH = H2O + O2 : 1.351923E-10 ;
24	{20.} HO2 + HO2 = H2O2 + O2 : 2.769464E-12 ;
25	{21.} HO2 + HO2 + H2O = H2O2 + O2 + H2O : 3.515415E-29 ;
26	{22.} H2O2 + OH = H2O + HO2 : 1.494801E-12 ;
27	{23.} NO + O3 = NO2 + O2 : 6.062488E-15 ;
28	{24.} NO + HO2 = NO2 + OH : 1.042107E-11 ;
29	{25.} NO2 + O = NO + O2 : 1.068500E-11 ;
30	{26.} NO2 + O3 = NO3 + O2 : 4.699133E-18 ;
31	{27.} NO2 + OH = HNO3 : 3.724129E-13 ;
32	{28.} NO2 + HO2 = HNO4 : 2.690292E-14 ;
33	{29.} NO3 + O = O2 + NO2 : 1.000000E-11 ;
34	{30.} NO3 + NO = 2NO2 : 3.033154E-11 ;
35	{31.} NO3 + NO2 = N2O5 : 2.325973E-13 ;
36	{32.} N2O5 = NO2 + NO3 : 1.405991E-06 ;
37	{33.} HNO3 + OH = H2O + NO3 : 1.890063E-13 ;
38	{34.} HNO4 + OH = H2O + NO2 + O2 : 6.273406E-12 ;
39	{35.} HNO4 = HO2 + NO2 : 3.163299E-07 ;
40	{36.} N2O5 = 2HNO3 : 0.000000E+00 ;
41	{37.} Cl + O2 = ClOO : 3.032678E-16 ;
42	{38.} Cl + O3 = ClO + O2 : 9.878682E-12 ;
43	{39.} Cl + H2 = HCl + H : 2.696898E-15 ;
44	{40.} Cl + HO2 = HCl + O2 : 3.639785E-11 ;
45	{41.} Cl + HO2 = OH + ClO : 6.357771E-12 ;
46	{42.} Cl + H2O2 = HCl + HO2 : 1.899010E-13 ;
47	{43.} ClO + O = Cl + O2 : 4.009038E-11 ;
48	{44.} ClO + OH = HO2 + Cl : 1.808230E-11 ;
49	{45.} ClO + OH = HCl + O2 : 0.000000E+00 ;
50	{46.} ClO + HO2 = O2 + HOCl : 8.718280E-12 ;
51	{47.} ClO + NO = NO2 + Cl : 2.127376E-11 ;
52	{48.} ClO + NO2 = ClONO2 : 2.886454E-14 ;
53	{49.} ClO + ClO = Cl + OClO : 1.201307E-15 ;
54	{50.} ClO + ClO = Cl + ClOO : 1.174783E-15 ;
55	{51.} ClO + ClO = Cl2 + O2 : 1.379878E-15 ;
56	{52.} ClO + ClO = Cl2O2 : 3.330338E-15 ;
57	{53.} ClOO = Cl + O2 : 1.694865E+04 ;
58	{54.} Cl2O2 = 2ClO : 4.773959E-04 ;
59	{55.} HCl + OH = H2O + Cl : 6.100684E-13 ;
60	{56.} HOCl + OH = H2O + ClO : 3.781814E-13 ;
61	{57.} ClONO2 + O = ClO + NO3 : 1.055174E-13 ;
62	{58.} ClONO2 + OH = HOCl + NO3 : 3.021112E-13 ;
63	{59.} ClONO2 + Cl = Cl2 + NO3 : 1.319240E-11 ;
64	{60.} ClONO2 = HOCl + HNO3 : 0.000000E+00 ;
65	{61.} Br + O3 = BrO + O2 : 6.185505E-13 ;
66	{62.} Br + HO2 = HBr + O2 : 1.249643E-12 ;
67	{63.} Br + CH2O = HBr + HCO : 6.185505E-13 ;
68	{64.} BrO + O = Br + O2 : 4.990544E-11 ;
69	{65.} BrO + HO2 = HOBr + O2 : 4.918275E-11 ;
70	{66.} BrO + NO = Br + NO2 : 2.583341E-11 ;
71	{67.} BrO + NO2 = BrONO2 : 7.684217E-14 ;
72	{68.} BrO + ClO = Br + OClO : 9.497781E-12 ;
73	{69.} BrO + ClO = Br + ClOO : 7.213454E-12 ;
74	{70.} BrO + ClO = BrCl + O2 : 1.172819E-12 ;
75	{71.} BrO + BrO = 2Br + O2 : 2.467250E-12 ;
76	{72.} HBr + OH = Br + H2O : 1.100000E-11 ;
77	{73.} CO + OH = H : 1.502401E-13 ;
78	{74.} CH4 + OH = CH3 + H2O : 1.532251E-15 ;
79	{75.} CH2O + OH = HCO + H2O : 1.000000E-11 ;
80	{76.} CH2O + O = HCO + OH : 4.501231E-14 ;
81	{77.} Cl + CH4 = CH3 + HCl : 3.334368E-14 ;
82	{78.} Cl + CH2O = HCl + HCO : 7.153519E-11 ;
83	{79.} HCO + O2 = CO + HO2 : 6.250373E-12 ;
84	{80.} CH3 + O2 = CH3O2 : 5.883651E-14 ;
85	{81.} CH3O + O2 = CH2O + HO2 : 9.377921E-16 ;
86	{82.} CH3O2 + NO = CH3O + NO2 : 8.851990E-12 ;
87	{83.} CH3O2 + HO2 = CH3OOH + O2 : 1.044377E-11 ;
88	{84.} CH3OOH + OH = CH3O2 + H2O : 6.182046E-12 ;
89
90	{ 1.} O2 + hv = 2O : 2.643E-10 * SUNSUNSUN ;
91	{ 2.} O3 + hv = O + O2 : 6.120E-04 * SUN ;
92	{ 3.} O3 + hv = O1D + O2 : 1.070E-03 * SUN*SUN ;
93	{ 4.} HO2 + hv = OH + O : 1.817E-04 * SUN*SUN ;
94	{ 5.} H2O2 + hv = 2OH : 3.537E-05 * SUN ;
95	{ 6.} NO2 + hv = NO + O : 1.289E-02 * SUN ;
96	{ 7.} NO3 + hv = NO2 + O : 2.359E-01 * SUN ;
97	{ 8.} NO3 + hv = NO + O2 : 2.883E-02 * SUN ;
98	{ 9.} N2O5 + hv = NO2 + NO3 : 2.594E-04 * SUN*SUN ;
99	{10.} HNO3 + hv = OH + NO2 : 5.269E-05 * SUN*SUN ;
100	{11.} HNO4 + hv = OH + NO3 : 4.557E-05 * SUN*SUN ;
101	{12.} HNO4 + hv = HO2 + NO2 : 9.113E-05 * SUN*SUN ;
102	{13.} Cl2 + hv = 2Cl : 3.692E-03 * SUN ;
103	{14.} OClO + hv = O + ClO : 1.243E-01 * SUN ;
104	{15.} Cl2O2 + hv = Cl + ClOO : 3.421E-03 * SUN ;
105	{16.} HOCl + hv = OH + Cl : 4.606E-04 * SUN ;
106	{17.} ClONO2 + hv = Cl + NO3 : 2.254E-04 * SUN*SUN ;
107	{18.} ClONO2 + hv = Cl + NO2 + O : 2.505E-05 * SUN*SUN ;
108	{19.} BrCl + hv = Br + Cl : 1.867E-02 * SUN ;
109	{20.} BrO + hv = Br + O : 5.950E-02 * SUN ;
110	{21.} HOBr + hv = Br + OH : 1.284E-03 * SUN ;
111	{22.} BrONO2 + hv = Br + NO3 : 2.074E-03 * SUN ;
112	{23.} CH2O + hv = HCO + H : 7.553E-05 * SUN ;
113	{24.} CH2O + hv = CO + H2 : 8.303E-05 * SUN ;
114	{25.} CH3OOH + hv = CH3O + OH : 2.285E-05 * SUN ;
115

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