1 | #Equations |
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2 | |
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3 | {1} NO2 + hv = NO + O3P : 1.0*SUN; |
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4 | {2} O3P + O2 + AIR = O3 : ARR(5.68e-34,0.0,-2.80); |
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5 | {3} O3P + O3 = 2O2 : ARR(8.00e-12,2060.0,0.0); |
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6 | {4} O3P + NO + AIR = NO2 : ARR(1.00e-31,0.0,-1.60); |
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7 | {5} O3P + NO2 = NO : ARR(6.50e-12,-120.0,0.0); |
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8 | {6} O3P + NO2 = NO3 : FALL(9.00e-32,0.0,-2.00,2.20e-11,0.0,0.0,0.80); |
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9 | {7} O3 + NO = NO2 : ARR(1.80e-12,1370.0,0.0); |
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10 | {8} O3 + NO2 = NO3 : ARR(1.40e-13,2470.0,0.0); |
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11 | {9} NO + NO3 = 2NO2 : ARR(1.80e-11,-110.0,0.0); |
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12 | {10} NO + NO + O2 = 2NO2 : ARR(3.30e-39,-530.0,0.0); |
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13 | {11} NO2 + NO3 = N2O5 : FALL(2.80e-30,0.0,-3.50,2.00e-12,0.0,0.20,0.45); |
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14 | {12} N2O5 = NO2 + NO3 : FALL(1.e-3,11000.0,-3.5,9.7e14,11080.0,0.1,0.45); |
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15 | {13} N2O5 + H2O = 2HNO3 : (2.60e-22); |
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16 | {14} NO2 + NO3 = NO + NO2 : ARR(4.50e-14,1260.0,0.0); |
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17 | {15} NO3 + hv = NO : 1.0*SUN; |
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18 | {16} NO3 + hv = NO2 + O3P : 1.0*SUN; |
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19 | {17} O3 + hv = O3P : 1.0*SUN; |
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20 | {18} O3 + hv = O1D : 1.0*SUN; |
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21 | {19} O1D + H2O = 2OH : (2.20e-10); |
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22 | {20} O1D + AIR = O3P : ARR(2.09e-11,-95.0,0.0); |
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23 | {21} OH + NO = HONO : FALL(7.00e-31,0.0,-2.60,3.60e-11,0.0,-0.10,0.60); |
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24 | {22} HONO + hv = OH + NO : 1.0*SUN; |
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25 | {23} HONO + hv = HO2 + NO2 : 1.0*SUN; |
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26 | {24} OH + HONO = NO2 : ARR(2.70e-12,-260.0,0.0); |
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27 | {25} OH + NO2 = HNO3 : FALL(2.43e-30, 0.0,-3.10,1.67e-11,0.0,-2.10,0.60); |
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28 | {26} OH + NO3 = HO2 + NO2 : (2.00e-11); |
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29 | {27} OH + HNO3 = NO3 : EP2(7.20e-15,-785.0,4.10e-16,-1440.0,1.90e-33,-725.0); |
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30 | {28} HNO3 + hv = OH + NO2 : 1.0*SUN; |
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31 | {29} OH + CO = HO2 : EP3(1.30e-13,0.0,3.19e-33,0.0); |
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32 | {30} OH + O3 = HO2 : ARR(1.90e-12,1000.0,0.0); |
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33 | {31} HO2 + NO = OH + NO2 : ARR(3.40e-12,-270.0,0.0); |
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34 | {32} HO2 + NO2 = HNO4 : FALL(1.80e-31,0.0,-3.20,4.70e-12,0.0,0.0,0.60); |
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35 | {33} HNO4 = HO2 + NO2 : FALL(4.10e-05,10650.0,0.0,5.7e+15,11170.0,0.0,0.5); |
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36 | {34} HNO4 + hv = 0.61HO2 + 0.61NO2 + 0.39OH + |
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37 | 0.39NO3 : 1.0*SUN; |
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38 | {35} HNO4 + OH = NO2 : ARR(1.50e-12,-360.0,0.0); |
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39 | {36} HO2 + O3 = OH : ARR(1.40e-14,600.0,0.0); |
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40 | {37} HO2 + HO2 = H2O2 : EP3(2.20e-13,-600.0,1.85e-33,-980.0); |
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41 | //{38} HO2 + HO2 + H2O = H2O2 : EP3(3.08e-34,-2800.0,2.59e-54,-3180.0); |
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42 | {38} HO2 + HO2 + H2O = H2O2 : EP3(3.08e-34,-2800.0,2.59e-38,-3180.0); |
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43 | {39} NO3 + HO2 = 0.8OH + 0.8NO2 + 0.2HNO3 : (4.00e-12); |
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44 | {40} NO3 + NO3 = 2NO2 : ARR(8.50e-13,2450.0,0.0); |
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45 | {41} H2O2 + hv = 2OH : 1.0*SUN; |
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46 | {42} H2O2 + OH = HO2 : ARR(2.90e-12,160.0,0.0); |
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47 | {43} OH + HO2 = H2O + O2 : ARR(4.80e-11,-250.0,0.0); |
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48 | {44} OH + SO2 = HO2 + H2SO4 : FALL(4.00e-31,0.0,-3.30,2.00e-12,0.0,0.0,0.45); |
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49 | {45} OH + H2 = HO2 : ARR(7.70e-12,2100.0,0.0); |
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50 | {46} C_O2 + NO = NO2 + HCHO + HO2 : ARR(2.80e-12,-285.0,0.0); |
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51 | {47} C_O2 + HO2 = COOH : ARR(3.80e-13,-780.0,0.0); |
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52 | {48} C_O2 + NO3 = HCHO + HO2 + NO2 : (1.30e-12); |
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53 | {49} C_O2 + C_O2 = MEOH + HCHO : ARR(2.45e-14,-710.0,0.0); |
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54 | {50} C_O2 + C_O2 = 2HCHO + 2HO2 : ARR(5.90e-13,509.0,0.0); |
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55 | {51} RO2_R + NO = NO2 + HO2 : ARR(2.70e-12,-360.0,0.0); |
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56 | {52} RO2_R + HO2 = ROOH : ARR(1.90e-13,-1300.0,0.0); |
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57 | {53} RO2_R + NO3 = NO2 + HO2 : (2.30e-12); |
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58 | {54} RO2_R + C_O2 = HO2 + 0.75HCHO + |
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59 | 0.25MEOH : (2.00e-13); |
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60 | {55} RO2_R + RO2_R = HO2 : (3.50e-14); |
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61 | {56} R2O2 + NO = NO2 : ARR(2.70e-12,-360.0,0.0); {1.0*RCONST(51);} |
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62 | {57} R2O2 + HO2 = HO2 : ARR(1.90e-13,-1300.0,0.0); {1.0*RCONST(52);} |
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63 | {58} R2O2 + NO3 = NO2 : (2.30e-12); {1.0*RCONST(53);} |
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64 | {59} R2O2 + C_O2 = C_O2 : (2.00e-13); {1.0*RCONST(54);} |
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65 | {60} R2O2 + RO2_R = RO2_R : (3.50e-14); {1.0*RCONST(55);} |
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66 | {61} R2O2 + R2O2 = 2R2O2 : (0.0); |
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67 | {62} RO2_N + NO = RNO3 : ARR(2.70e-12,-360.0,0.0); {1.0*RCONST(51);} |
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68 | {63} RO2_N + HO2 = ROOH : ARR(1.90e-13,-1300.0,0.0); {1.0*RCONST(52);} |
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69 | {64} RO2_N + C_O2 = HO2 + 0.25MEOH + |
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70 | 0.5MEK + 0.5PROD2 + 0.75HCHO : (2.00e-13); {1.0*RCONST(54);} |
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71 | {65} RO2_N + NO3 = NO2 + HO2 + MEK : (2.30e-12); {1.0*RCONST(53);} |
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72 | {66} RO2_N + RO2_R = HO2 + 0.5MEK + |
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73 | 0.5PROD2 : (3.50e-14); {1.0*RCONST(55);} |
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74 | {67} RO2_N + R2O2 = RO2_N : (3.50e-14); {1.0*RCONST(55);} |
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75 | {68} RO2_N + RO2_N = MEK + HO2 + PROD2 : (3.50e-14); {1.0*RCONST(55);} |
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76 | {69} CCO_O2 + NO2 = PAN : FALL(2.70e-28,0.0,-7.10,1.20e-11,0.0,-0.90,0.30); |
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77 | {70} PAN = CCO_O2 + NO2 : FALL(4.90e-3,12100.0,0.0,4.0e+16,13600.0,0.,0.3); |
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78 | {71} CCO_O2 + NO = C_O2 + NO2 : ARR(7.80e-12,-300.0,0.0); |
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79 | {72} CCO_O2 + HO2 = 0.75CCO_OOH + |
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80 | 0.25CCO_OH + 0.25O3 : ARR(4.30e-13,-1040.0,0.0); |
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81 | {73} CCO_O2 + NO3 = C_O2 + NO2 : (4.00e-12); |
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82 | {74} CCO_O2 + C_O2 = CCO_OH + HCHO : ARR(1.80e-12,-500.0,0.0); |
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83 | {75} CCO_O2 + RO2_R = CCO_OH : (7.50e-12); |
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84 | {76} CCO_O2 + R2O2 = CCO_O2 : (7.50e-12); |
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85 | {77} CCO_O2 + RO2_N = CCO_OH + PROD2 : (7.50e-12); |
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86 | {78} CCO_O2 + CCO_O2 = 2C_O2 : ARR(2.90e-12,-500.0,0.0); |
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87 | {79} RCO_O2 + NO2 = PAN2 : ARR(1.20e-11,0.0,-0.90); |
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88 | {80} PAN2 = RCO_O2 + NO2 : ARR(2.00e+15,12800.0,0.0); |
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89 | {81} RCO_O2 + NO = NO2 + CCHO + RO2_R : ARR(1.25e-11,-240.0,0.0); |
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90 | {82} RCO_O2 + HO2 = 0.75RCO_OOH + |
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91 | 0.25RCO_OH + 0.25O3 : ARR(4.30e-13,-1040.0,0.0); {1.0*RCONST(72);} |
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92 | {83} RCO_O2 + NO3 = NO2 + CCHO + RO2_R : (4.00e-12); {1.0*RCONST(73);} |
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93 | {84} RCO_O2 + C_O2 = RCO_OH + HCHO : ARR(1.80e-12,-500.0,0.0); {1.0*RCONST(74);} |
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94 | {85} RCO_O2 + RO2_R = RCO_OH : (7.50e-12); {1.0*RCONST(75);} |
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95 | {86} RCO_O2 + R2O2 = RCO_O2 : (7.50e-12); {1.0*RCONST(75);} |
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96 | {87} RCO_O2 + RO2_N = RCO_OH + PROD2 : (7.50e-12); {1.0*RCONST(75);} |
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97 | {88} RCO_O2 + CCO_O2 = C_O2 + CCHO + RO2_R : ARR(2.90e-12,-500.0,0.0); {1.0*RCONST(78);} |
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98 | {89} RCO_O2 + RCO_O2 = 2CCHO + 2RO2_R : ARR(2.90e-12,-500.0,0.0); {1.0*RCONST(78);} |
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99 | {90} BZCO_O2 + NO2 = PBZN : (1.37e-11); |
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100 | {91} PBZN = BZCO_O2 + NO2 : ARR(7.90e+16,14000.0,0.0); |
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101 | {92} BZCO_O2 + NO = NO2 + BZ_O + R2O2 : ARR(1.25e-11,-240.0,0.0); {1.0*RCONST(81);} |
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102 | {93} BZCO_O2 + HO2 = 0.75RCO_OOH + |
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103 | 0.25RCO_OH + 0.25O3 : ARR(4.30e-13,-1040.0,0.0); {1.0*RCONST(72);} |
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104 | {94} BZCO_O2 + NO3 = NO2 + BZ_O + R2O2 : (4.00e-12); {1.0*RCONST(73);} |
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105 | {95} BZCO_O2 + C_O2 = RCO_OH + HCHO : ARR(1.80e-12,-500.0,0.0); {1.0*RCONST(74);} |
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106 | {96} BZCO_O2 + RO2_R = RCO_OH : (7.50e-12); {1.0*RCONST(75);} |
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107 | {97} BZCO_O2 + R2O2 = BZCO_O2 : (7.50e-12); {1.0*RCONST(75);} |
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108 | {98} BZCO_O2 + RO2_N = RCO_OH + PROD2 : (7.50e-12); {1.0*RCONST(75);} |
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109 | {99} BZCO_O2 + CCO_O2 = C_O2 + BZ_O + R2O2 : ARR(2.90e-12,-500.0,0.0); {1.0*RCONST(78);} |
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110 | {100} BZCO_O2 + RCO_O2 = CCHO + RO2_R + |
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111 | BZ_O + R2O2 : ARR(2.90e-12,-500.0,0.0); {1.0*RCONST(78);} |
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112 | {101} BZCO_O2 + BZCO_O2 = 2BZ_O + 2R2O2: ARR(2.90e-12,-500.0,0.0); {1.0*RCONST(78);} |
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113 | {102} MA_RCO3 + NO2 = MA_PAN : ARR(1.20e-11,0.0,-0.90); {1.0*RCONST(79);} |
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114 | {103} MA_PAN = MA_RCO3 + NO2 : ARR(1.60e+16,13486.0,0.0); |
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115 | {104} MA_RCO3 + NO = NO2 + HCHO + CCO_O2 : ARR(1.25e-11,-240.0,0.0); {1.0*RCONST(81);} |
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116 | {105} MA_RCO3 + HO2 = 0.75RCO_OOH + |
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117 | 0.25RCO_OH + 0.25O3 : ARR(4.30e-13,-1040.0,0.0); {1.0*RCONST(72);} |
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118 | {106} MA_RCO3 + NO3 = NO2 + HCHO + CCO_O2 : (4.00e-12); {1.0*RCONST(73);} |
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119 | {107} MA_RCO3 + C_O2 = RCO_OH + HCHO : ARR(1.80e-12,-500.0,0.0); {1.0*RCONST(74);} |
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120 | {108} MA_RCO3 + RO2_R = RCO_OH : (7.50e-12); {1.0*RCONST(75);} |
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121 | {109} MA_RCO3 + R2O2 = MA_RCO3 : (7.50e-12); {1.0*RCONST(75);} |
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122 | {110} MA_RCO3 + RO2_N = 2RCO_OH : (7.50e-12); {1.0*RCONST(75);} |
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123 | {111} MA_RCO3 + CCO_O2 = C_O2 + HCHO + |
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124 | CCO_O2 : ARR(2.90e-12,-500.0,0.0); {1.0*RCONST(78);} |
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125 | {112} MA_RCO3 + RCO_O2 = HCHO + CCO_O2 + |
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126 | CCHO + RO2_R : ARR(2.90e-12,-500.0,0.0); {1.0*RCONST(78);} |
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127 | {113} MA_RCO3 + BZCO_O2 = HCHO + CCO_O2 + |
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128 | BZ_O + R2O2 : ARR(2.90e-12,-500.0,0.0); {1.0*RCONST(78);} |
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129 | {114} MA_RCO3 + MA_RCO3 = 2HCHO + 2CCO_O2 : ARR(2.90e-12,-500.0,0.0); {1.0*RCONST(78);} |
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130 | {115} TBU_O + NO2 = RNO3 : (2.40e-11); |
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131 | {116} TBU_O = ACET + C_O2 : ARR(7.50e+14,8152.0,0.0); |
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132 | {117} BZ_O + NO2 = NPHE : ARR(2.30e-11,-150.0,0.0); |
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133 | {118} BZ_O + HO2 = PHEN : ARR(1.90e-13,-1300.0,0.0); {1.0*RCONST(52);} |
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134 | {119} BZ_O = PHEN : (1.00e-03); |
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135 | {120} BZNO2_O + NO2 = 2XN + 6XC: ARR(7.50e+14,8152.0,0.0); {1.0*RCONST(116);} |
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136 | {121} BZNO2_O + HO2 = NPHE : ARR(2.30e-11,-150.0,0.0); {1.0*RCONST(117);} |
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137 | {122} BZNO2_O = NPHE : ARR(1.90e-13,-1300.0,0.0); {1.0*RCONST(118);} |
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138 | {123} HCHO + hv = 2HO2 + CO : 1.0*SUN; |
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139 | {124} HCHO + hv = CO : 1.0*SUN; |
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140 | {125} HCHO + OH = HO2 + CO : ARR(8.60e-12,-20.0,0.0); |
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141 | {126} HCHO + HO2 = HOCOO : ARR(9.70e-15,-625.0,0.0); |
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142 | {127} HOCOO = HO2 + HCHO : ARR(2.40e+12,7000.0,0.0); |
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143 | {128} HOCOO + NO = HCOOH + NO2 + HO2 : ARR(2.80e-12,-285.0,0.0); {1.0*RCONST(46);} |
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144 | {129} HCHO + NO3 = HNO3 + HO2 + CO : ARR(2.00e-12,2431.0,0.0); |
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145 | {130} CCHO + OH = CCO_O2 : ARR(5.60e-12,-310.0,0.0); |
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146 | {131} CCHO +hv = CO + HO2 + C_O2 : 1.0*SUN; |
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147 | {132} CCHO + NO3 = HNO3 + CCO_O2 : ARR(1.40e-12,1860.0,0.0); |
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148 | {133} RCHO + OH = 0.034RO2_R + 0.001RO2_N + |
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149 | 0.965RCO_O2 + 0.034CO+ 0.034CCHO : (2.00e-11); |
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150 | {134} RCHO + hv = CCHO + RO2_R + CO + HO2 : 1.0*SUN; |
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151 | {135} RCHO + NO3 = HNO3 + RCO_O2 : ARR(1.40e-12,1771.0,0.0); |
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152 | {136} ACET + OH = HCHO + CCO_O2 + R2O2 : ARR(1.10e-12,520.0,0.0); |
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153 | {137} ACET + hv = CCO_O2 + C_O2 : 1.0*SUN; |
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154 | {138} MEK + OH = 0.37RO2_R + 0.042RO2_N + |
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155 | 0.616R2O2+ 0.492CCO_O2 + |
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156 | 0.096RCO_O2 + 0.115HCHO + |
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157 | 0.482CCHO + 0.37RCHO : ARR(1.30e-12,25.0,2.0); |
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158 | {139} MEK + hv = CCO_O2 + CCHO + RO2_R : 1.50e-1*SUN; |
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159 | {140} MEOH + OH = HCHO + HO2 : ARR(3.10e-12,360.0,2.0); |
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160 | {141} ETOH + OH = 0.95HO2 + 0.05RO2_R + |
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161 | 0.081HCHO + 0.96CCHO : ARR(0.0,0.0,1.0); |
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162 | {142} COOH + OH = 0.35HCHO + 0.35OH + |
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163 | 0.65C_O2 : ARR(2.90e-12,-190.0,0.0); |
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164 | {143} COOH + hv = HCHO + HO2 + OH : 1.0*SUN; |
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165 | {144} ROOH + OH = RCHO + 0.34RO2_R + |
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166 | 0.66OH : (1.10e-11); |
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167 | {145} ROOH + hv = RCHO + HO2 + OH : 1.0*SUN; |
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168 | {146} GLY + hv = 2CO+ 2HO2 : 1.0*SUN; |
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169 | {147} GLY + hv = HCHO + CO : 6.00e-3*SUN; |
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170 | {148} GLY + OH = 0.63HO2 + 1.26CO+ |
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171 | 0.37RCO_O2 : (1.10e-11); |
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172 | {149} GLY + NO3 = HNO3 + 0.63HO2 + |
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173 | 1.26CO+ 0.37RCO_O2 : ARR(2.80e-12,2376.0,0.0); |
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174 | {150} MGLY + hv = HO2 + CO + CCO_O2 : 1.0*SUN; |
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175 | {151} MGLY + OH = CO + CCO_O2 : (1.50e-11); |
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176 | {152} MGLY + NO3 = HNO3 + CO + CCO_O2 : ARR(1.40e-12,1895.0,0.0); |
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177 | {153} BACL + hv = 2CCO_O2 : 1.0*SUN; |
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178 | {154} PHEN + OH = 0.24BZ_O + 0.76RO2_R + |
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179 | 0.23GLY : (2.63e-11); |
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180 | {155} PHEN + NO3 = HNO3 + BZ_O : (3.78e-12); |
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181 | {156} CRES + OH = 0.24BZ_O + 0.76RO2_R + |
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182 | 0.23MGLY : (4.20e-11); |
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183 | {157} CRES + NO3 = HNO3 + BZ_O : (1.37e-11); |
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184 | {158} NPHE + NO3 = HNO3 + BZNO2_O : (2.63e-11); {1.0*RCONST(154);} |
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185 | {159} BALD + OH = BZCO_O2 : (1.29e-11); |
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186 | {160} BALD + hv = 7XC: 5.00e-2*SUN; |
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187 | {161} BALD + NO3 = HNO3 + BZCO_O2 : ARR(1.40e-12,1872.0,0.0); |
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188 | {162} METHACRO + OH = 0.5RO2_R + 0.416CO+ |
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189 | 0.084HCHO + 0.416MEK + |
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190 | 0.084MGLY + 0.5MA_RCO3 : ARR(1.86e-11,-176.0,0.0); |
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191 | {163} METHACRO + O3 = 0.008HO2 + 0.1RO2_R + |
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192 | 0.208OH + 0.1RCO_O2 + 0.45CO+ |
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193 | 0.2HCHO + 0.9MGLY + 0.333HCOOH : ARR(1.36e-15,2114.0,0.0); |
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194 | {164} METHACRO + NO3 = 0.5HNO3 + 0.5RO2_R + |
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195 | 0.5CO+ 0.5MA_RCO3 : ARR(1.50e-12,1726.0,0.0); |
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196 | {165} METHACRO + O3P = RCHO : (6.34e-12); |
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197 | {166} METHACRO + hv = 0.34HO2 + 0.33RO2_R + |
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198 | 0.33OH + 0.67CCO_O2 + 0.67CO+ |
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199 | 0.67HCHO + 0.33MA_RCO3 : 4.10e-3*SUN; |
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200 | {167} MVK + OH = 0.3RO2_R + 0.025RO2_N + |
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201 | 0.675R2O2+ 0.675CCO_O2 + |
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202 | 0.3HCHO + 0.675RCHO + 0.3MGLY : ARR(4.14e-12,-453.0,0.0); |
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203 | {168} MVK + O3 = 0.064HO2 + 0.05RO2_R + |
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204 | 0.164OH + 0.05RCO_O2 + 0.475CO+ |
---|
205 | 0.1HCHO + 0.95MGLY + 0.351HCOOH : ARR(7.51e-16,1520.0,0.0); |
---|
206 | {169} MVK + O3P = 0.45RCHO + 0.55MEK : (4.32e-12); |
---|
207 | {170} MVK + hv = 0.3C_O2 + 0.7CO+ 0.7PROD2 + |
---|
208 | 0.3MA_RCO3 : 2.10e-3*SUN; |
---|
209 | {171} ISOPROD + OH = 0.67RO2_R + |
---|
210 | 0.041RO2_N + 0.289MA_RCO3 + |
---|
211 | 0.336CO+ 0.055HCHO + 0.129CCHO + |
---|
212 | 0.013RCHO + 0.15MEK + 0.332PROD2 + |
---|
213 | 0.15GLY + 0.174MGLY : (6.19e-11); |
---|
214 | {172} ISOPROD + O3 = 0.4HO2 + 0.048RO2_R + |
---|
215 | 0.048RCO_O2 + 0.285OH + |
---|
216 | 0.498CO+ 0.125HCHO + 0.047CCHO + |
---|
217 | 0.21MEK + 0.023GLY + 0.742MGLY + |
---|
218 | 0.1HCOOH + 0.372RCO_OH : (4.18e-18); |
---|
219 | {173} ISOPROD + NO3 = 0.799RO2_R + |
---|
220 | 0.051RO2_N + 0.15MA_RCO3 + 0.572CO+ |
---|
221 | 0.15HNO3 + 0.227HCHO + 0.218RCHO + |
---|
222 | 0.008MGLY + 0.572RNO3 : (1.00e-13); |
---|
223 | {174} ISOPROD + hv = 1.233HO2 + 0.467CCO_O2 + |
---|
224 | 0.3RCO_O2 + 1.233CO+ 0.3HCHO + |
---|
225 | 0.467CCHO + 0.233MEK : 4.10e-3*SUN; |
---|
226 | {175} PROD2 + OH = 0.379HO2 + 0.473RO2_R + |
---|
227 | 0.07RO2_N + 0.029CCO_O2 + |
---|
228 | 0.049RCO_O2 + 0.213HCHO + |
---|
229 | 0.084CCHO + 0.558RCHO + |
---|
230 | 0.115MEK + 0.329PROD2 : (1.50e-11); |
---|
231 | {176} PROD2 + hv = 0.96RO2_R + 0.04RO2_N + |
---|
232 | 0.515R2O2+ 0.667CCO_O2 + |
---|
233 | 0.333RCO_O2 + 0.506HCHO + |
---|
234 | 0.246CCHO + 0.71RCHO : 2.00e-2*SUN; |
---|
235 | {177} RNO3 + OH = 0.338NO2 + 0.113HO2 + |
---|
236 | 0.376RO2_R + 0.173RO2_N + |
---|
237 | 0.596R2O2+ 0.01HCHO + |
---|
238 | 0.439CCHO + 0.213RCHO + |
---|
239 | 0.006ACET + 0.177MEK + |
---|
240 | 0.048PROD2 + 0.31RNO3 : (7.80e-12); |
---|
241 | {178} RNO3 + hv = NO2 + 0.341HO2 + 0.564RO2_R + |
---|
242 | 0.095RO2_N + 0.152R2O2+ 0.134HCHO + |
---|
243 | 0.431CCHO + 0.147RCHO + 0.02ACET + |
---|
244 | 0.243MEK + 0.435PROD2 : 1.0*SUN; |
---|
245 | {179} DCB1 + OH = RCHO + RO2_R + CO : (5.00e-11); |
---|
246 | {180} DCB1 + O3 = 1.5HO2 + 0.5OH + |
---|
247 | 1.5CO + GLY : (2.00e-18); |
---|
248 | {181} DCB2 + OH = R2O2 + RCHO + CCO_O2 : (5.00e-11); |
---|
249 | {182} DCB2 + hv = RO2_R + 0.5CCO_O2 + 0.5HO2 + |
---|
250 | CO + R2O2 + 0.5GLY + 0.5MGLY : 3.65e-1*SUN; |
---|
251 | {183} DCB3 + OH = R2O2 + RCHO + CCO_O2 : (5.00e-11); |
---|
252 | {184} DCB3 + hv = RO2_R + 0.5CCO_O2 + 0.5HO2 + |
---|
253 | CO + R2O2 + 0.5GLY + 0.5MGLY : 7.28*SUN; |
---|
254 | {185} CH4 + OH = C_O2 : ARR(2.15e-12,1735.0,0.0); |
---|
255 | {186} ETHENE + OH = RO2_R + 1.61HCHO + |
---|
256 | 0.195CCHO : ARR(1.96e-12,-438.0,0.0); |
---|
257 | {187} ETHENE + O3 = 0.12OH + 0.12HO2 + |
---|
258 | 0.5CO+ HCHO + 0.37HCOOH : ARR(9.14e-15,2580.0,0.0); |
---|
259 | {188} ETHENE + NO3 = RO2_R + RCHO : ARR(4.39e-13,2282.0,2.0); |
---|
260 | {189} ETHENE + O3P = 0.5HO2 + 0.2RO2_R + |
---|
261 | 0.3C_O2 + 0.491CO+ 0.191HCHO + |
---|
262 | 0.25CCHO + 0.009GLY : ARR(1.04e-11,792.0,0.0); |
---|
263 | {190} ISOPRENE + OH = 0.907RO2_R + |
---|
264 | 0.093RO2_N + 0.079R2O2+ |
---|
265 | 0.624HCHO + 0.23METHACRO + |
---|
266 | 0.32MVK + 0.357ISOPROD : ARR(2.50e-11,-408.0,0.0); |
---|
267 | {191} ISOPRENE + O3 = 0.266OH + |
---|
268 | 0.066RO2_R + 0.008RO2_N + |
---|
269 | 0.126R2O2+ 0.192MA_RCO3 + |
---|
270 | 0.275CO+ 0.592HCHO + 0.1PROD2 + |
---|
271 | 0.39METHACRO + 0.16MVK + |
---|
272 | 0.204HCOOH + 0.15RCO_OH : ARR(7.86e-15,1912.0,0.0); |
---|
273 | {192} ISOPRENE + NO3 = 0.187NO2 + |
---|
274 | 0.749RO2_R + 0.064RO2_N + |
---|
275 | 0.187R2O2+ 0.936ISOPROD : ARR(3.03e-12,448.0,0.0); |
---|
276 | {193} ISOPRENE + O3P = 0.01RO2_N + |
---|
277 | 0.24R2O2+ 0.25C_O2 + 0.24MA_RCO3 + |
---|
278 | 0.24HCHO + 0.75PROD2 : (3.60e-11); |
---|
279 | {194} TERP + OH = 0.75RO2_R + 0.25RO2_N + |
---|
280 | 0.5R2O2+ 0.276HCHO + |
---|
281 | 0.474RCHO + 0.276PROD2 : ARR(1.83e-11,-449.0,0.0); |
---|
282 | {195} TERP + O3 = 0.567OH + 0.033HO2 + |
---|
283 | 0.031RO2_R + 0.18RO2_N + |
---|
284 | 0.729R2O2+ 0.123CCO_O2 + |
---|
285 | 0.201RCO_O2 + 0.157CO+ |
---|
286 | 0.235HCHO + 0.205RCHO + 0.13ACET + |
---|
287 | 0.276PROD2 + 0.001GLY + 0.031BACL + |
---|
288 | 0.103HCOOH + 0.189RCO_OH : ARR(1.08e-15,821.0,0.0); |
---|
289 | {196} TERP + NO3 = 0.474NO2 + |
---|
290 | 0.276RO2_R + 0.25RO2_N + |
---|
291 | 0.75R2O2+ 0.474RCHO + 0.276RNO3 : ARR(3.66e-12,-175.0,0.0); |
---|
292 | {197} TERP + O3P = 0.147RCHO + 0.853PROD2 : (3.27e-11); |
---|
293 | {198} C2H6 + OH = RO2_R + CCHO : ARR(1.37e-12,498.0,2.0); |
---|
294 | {199} C3H8 + OH = 0.965RO2_R + 0.035RO2_N + |
---|
295 | 0.261RCHO + 0.704ACET : ARR(0.0,0.0,1.0); |
---|
296 | {200} C2H2 + OH = 0.603OH + 0.297HO2 + |
---|
297 | 0.1RO2_R + 0.393CO + 0.096HCHO + |
---|
298 | 0.607GLY + 0.297HCOOH : ARR(9.87e-12,671.0,0.0); |
---|
299 | {201} ALK3 + OH = 0.695RO2_R + 0.07RO2_N + |
---|
300 | 0.559R2O2+ 0.236TBU_O + 0.026HCHO + |
---|
301 | 0.445CCHO + 0.122RCHO + 0.024ACET + |
---|
302 | 0.332MEK : ARR(1.019e-11,434.0,0.0); |
---|
303 | {202} ALK4 + OH = 0.835RO2_R + 0.143RO2_N + |
---|
304 | 0.936R2O2+ 0.011C_O2 + 0.011CCO_O2 + |
---|
305 | 0.002CO+ 0.024HCHO + 0.455CCHO + |
---|
306 | 0.244RCHO + 0.452ACET + 0.11MEK + |
---|
307 | 0.125PROD2 : ARR(5.946e-12,91.0,0.0); |
---|
308 | {203} ALK5 + OH = 0.653RO2_R + 0.347RO2_N + |
---|
309 | 0.948R2O2+ 0.026HCHO + 0.099CCHO + |
---|
310 | 0.204RCHO + 0.072ACET + 0.089MEK + |
---|
311 | 0.417PROD2 : ARR(1.112e-11,52.0,0.0); |
---|
312 | {204} ARO1 + OH = 0.224HO2 + 0.765RO2_R + |
---|
313 | 0.011RO2_N + 0.055PROD2 + 0.118GLY + |
---|
314 | 0.119MGLY + 0.017PHEN + 0.207CRES + |
---|
315 | 0.059BALD + 0.491DCB1 + 0.108DCB2 + |
---|
316 | 0.051DCB3 : ARR(1.81e-12,-355.0,0.0); |
---|
317 | {205} ARO2 + OH = 0.187HO2 + 0.804RO2_R + |
---|
318 | 0.009RO2_N + 0.097GLY + 0.287MGLY + |
---|
319 | 0.087BACL + 0.187CRES + 0.05BALD + |
---|
320 | 0.561DCB1 + 0.099DCB2 + 0.093DCB3 : (2.640e-11); |
---|
321 | {206} OLE1 + OH = 0.91RO2_R + 0.09RO2_N + |
---|
322 | 0.205R2O2+ 0.732HCHO + 0.294CCHO + |
---|
323 | 0.497RCHO + 0.005ACET + 0.119PROD2 : ARR(7.095e-12,-451.0,0.0); |
---|
324 | {207} OLE1 + O3 = 0.155OH + 0.056HO2 + |
---|
325 | 0.022RO2_R + 0.001RO2_N + |
---|
326 | 0.076C_O2 + 0.345CO+ 0.5HCHO + |
---|
327 | 0.154CCHO + 0.363RCHO + 0.001ACET + |
---|
328 | 0.215PROD2 + 0.185HCOOH + |
---|
329 | 0.05CCO_OH + 0.119RCO_OH : ARR(2.617e-15,1640.0,0.0); |
---|
330 | {208} OLE1 + NO3 = 0.824RO2_R + 0.176RO2_N + |
---|
331 | 0.488R2O2+ 0.009CCHO + 0.037RCHO + |
---|
332 | 0.024ACET + 0.511RNO3 : ARR(4.453e-14,376.0,0.0); |
---|
333 | {209} OLE1 + O3P = 0.45RCHO + 0.437MEK + |
---|
334 | 0.113PROD2 : ARR(1.074e-11,234.0,0.0); |
---|
335 | {210} OLE2 + OH = 0.918RO2_R + 0.082RO2_N + |
---|
336 | 0.001R2O2+ 0.244HCHO + 0.732CCHO + |
---|
337 | 0.511RCHO + 0.127ACET + 0.072MEK + |
---|
338 | 0.061BALD + 0.025METHACRO + |
---|
339 | 0.025ISOPROD : ARR(1.743e-11,-384.0,0.0); |
---|
340 | {211} OLE2 + O3 = 0.378OH + 0.003HO2 + |
---|
341 | 0.033RO2_R + 0.002RO2_N + 0.137R2O2+ |
---|
342 | 0.197C_O2 + 0.137CCO_O2 + |
---|
343 | 0.006RCO_O2 + 0.265CO+ 0.269HCHO + |
---|
344 | 0.456CCHO + 0.305RCHO + 0.045ACET + |
---|
345 | 0.026MEK + 0.043PROD2 + 0.042BALD + |
---|
346 | 0.026METHACRO + 0.019MVK + |
---|
347 | 0.073HCOOH + 0.129CCO_OH + |
---|
348 | 0.247RCO_OH : ARR(5.022e-16,461.0,0.0); |
---|
349 | {212} OLE2 + NO3 = 0.391NO2 + 0.442RO2_R + |
---|
350 | 0.136RO2_N + 0.711R2O2+ 0.03C_O2 + |
---|
351 | 0.079HCHO + 0.507CCHO + 0.151RCHO + |
---|
352 | 0.102ACET + 0.001MEK + 0.015BALD + |
---|
353 | 0.048MVK + 0.321RNO3 : (7.265e-13); |
---|
354 | {213} OLE2 + O3P = 0.013HO2 + 0.012RO2_R + |
---|
355 | 0.001RO2_N + 0.012CO+ 0.069RCHO + |
---|
356 | 0.659MEK + 0.259PROD2 + |
---|
357 | 0.012METHACRO : (2.085e-11); |
---|
358 | {214} C2H2 + O3 = 0.5OH + 1.5HO2 + |
---|
359 | 1.5CO + 0.5CO2 : (2.20e-10); |
---|
360 | {215} C3H6 + OH = 0.984RO2_R + 0.016RO2_N + |
---|
361 | 0.984HCHO + 0.984CCHO + 0.048XC : (2.20e-10); |
---|
362 | {216} C3H6 + O3 = 0.32OH + 0.06HO2 + |
---|
363 | 0.26C_O2 + 0.51CO + 0.135CO2 + 0.5HCHO + |
---|
364 | 0.5CCHO + 0.185HCOOH + 0.17CCO_OH + 0.07XC: (2.20e-10); |
---|
365 | {217} C3H6 + NO3 = 0.949RO2_R + 0.051RO2_N + |
---|
366 | 2.693XC + 1.0XN : (2.20e-10); |
---|
367 | {218} C3H6 + O3P = 0.45RCHO + 0.55MEK + |
---|
368 | 0.55XC: (2.20e-10); |
---|
369 | {219} SO2 = H2SO4 : (2.20e-10); |
---|
370 | {220} HO2 = AIR : (7.00e-7); |
---|
371 | {221} SO2 = AIR : (2.20e-10); |
---|
372 | {222} H2SO4 = AIR : (2.20e-10); |
---|
373 | {223} HNO3 = AIR : (2.20e-10); |
---|
374 | {224} H2O2 = AIR : (2.20e-10); |
---|
375 | {225} BC = AIR : (7.00e-7); |
---|
376 | {226} OC = AIR : (7.00e-7); |
---|
377 | {227} SSF = AIR : (7.00e-7); |
---|
378 | {228} SSC = AIR : (7.00e-7); |
---|
379 | {229} PM10 = AIR : (7.00e-7); |
---|
380 | {230} PM25 = AIR : (7.00e-7); |
---|
381 | {231} DST1 = AIR : (7.00e-7); |
---|
382 | {232} DST2 = AIR : (7.00e-7); |
---|
383 | {233} DST3 = AIR : (7.00e-7); |
---|
384 | {234} DMS = AIR : (7.00e-7); |
---|
385 | {235} CO2 = AIR : (7.00e-7); |
---|
386 | |
---|