#EQUATIONS { 1.} NO2 + hv = NO + O : 8.89E-3*SUN ; { 2.} O {+ O2 + M} = O3 : ARR2(1.4E+3, 1175.0) ; { 3.} O3 + NO = NO2 : ARR2(1.8E-12, -1370.0) ; { 4.} O + NO2 = NO : 9.3E-12 ; { 5.} O + NO2 = NO3 : ARR2(1.6E-13, 687.0) ; { 6.} O + NO = NO2 : ARR2(2.2E-13, 602.0) ; { 7.} O3 + NO2 = NO3 : ARR2(1.2E-13, -2450.0) ; { 8.} O3 + hv = O : 4.0E-2*RCONST(1) ; { 9.} O3 + hv = O1D : 2.8E-3*RCONST(1) ; {10.} O1D = O : ARR2(1.9E+8, 390.0) ; {11.} O1D + H2O = 2OH : 2.2E-10 ; {12.} O3 + OH = HO2 : ARR2(1.6E-12, -940.0) ; {13.} O3 + HO2 = OH : ARR2(1.4E-14, -580.0) ; {14.} NO3 + hv = 0.89 NO2 + 0.89 O + 0.11 NO : 15.5*RCONST(1) ; {15.} NO3 + NO = 2 NO2 : ARR2(1.3E-11, 250.0) ; {16.} NO3 + NO2 = NO + NO2 : ARR2(2.5E-14, -1230.0) ; {17.} NO3 + NO2 = N2O5 : ARR2(5.3E-13, 256.0) ; {18.} N2O5 + H2O = 2 HNO3 : 1.3E-21 ; {19.} N2O5 = NO3 + NO2 : ARR2(3.5E+14, -10897.0) ; {20.} 2 NO = 2 NO2 : ARR2(1.8E-20, 530.0) ; {21.} NO + NO2 + H2O = 2 HONO : 4.4E-40 ; {22.} OH + NO = HONO : ARR2(4.5E-13, 806.0) ; {23.} HONO + hv = OH + NO : 0.17*RCONST(1) ; {24.} OH + HONO = NO2 : 6.6E-12 ; {25.} 2 HONO = NO + NO2 : 1.0E-20 ; {26.} OH + NO2 = HNO3 : ARR2(1.0E-12, 713.0) ; {27.} OH + HNO3 = NO3 : ARR2(5.1E-15, 1000.0) ; {28.} HO2 + NO = OH + NO2 : ARR2(3.7E-12, 240.0) ; {29.} HO2 + NO2 = PNA : ARR2(1.2E-13, 749.0) ; {30.} PNA = HO2 + NO2 : ARR2(4.8E+13, -10121.0) ; {31.} OH + PNA = NO2 : ARR2(1.3E-12, 380.0) ; {32.} 2 HO2 = H2O2 : ARR2(5.9E-14, 1150.0) ; {33.} 2 HO2 + H2O = H2O2 : ARR2(2.2E-38, 5800.0) ; {34.} H2O2 + hv = 2 OH : 7.1E-4*RCONST(1) ; {35.} OH + H2O2 = HO2 : ARR2(3.1E-12, -187.0) ; {36.} OH + CO = HO2 : 2.2E-13 ; {37.} HCHO + OH = HO2 + CO : 1.0E-11 ; {38.} HCHO + hv {+ 2 O2} = 2 HO2 + CO : 3.2E-3*RCONST(1) ; {39.} HCHO + hv = CO : 4.2E-3*RCONST(1) ; {40.} HCHO + O = OH + HO2 + CO : ARR2(3.0E-11, -1550.0) ; {41.} HCHO + NO3 = HNO3 + HO2 + CO : 6.3E-16 ; {42.} ALD2 + O = C2O3 + OH : ARR2(1.2E-11, -986.0) ; {43.} ALD2 + OH = C2O3 : ARR2(7.0E-12, 250.0) ; {44.} ALD2 + NO3 = C2O3 + HNO3 : 2.5E-15 ; {45.} ALD2 + hv {+ 2 O2} = HCHO + XO2 + CO + 2 HO2 : 4.5E-4*RCONST(1) ; {46.} C2O3 + NO = HCHO + XO2 + HO2 + NO2 : ARR2(5.4E-12, 250.0) ; {47.} C2O3 + NO2 = PAN : ARR2(8.0E-20, 5500.0) ; {48.} PAN = C2O3 + NO2 : ARR2(9.4E+16, -14000.0) ; {49.} 2 C2O3 = 2 HCHO + 2 XO2 + 2 HO2 : 2.0E-12 ; {50.} C2O3 + HO2 = 0.79 HCHO + 0.79 XO2 + 0.79 HO2 + 0.79 OH : 6.5E-12 ; {51.} OH = HCHO + XO2 + HO2 : ARR2(1.1E+2, -1710.0) ; {52.} PAR + OH = 0.87 XO2 + 0.13 XO2N + 0.11 HO2 + 0.11 ALD2 + 0.76 ROR - 0.11 PAR : 8.1E-13 ; {53.} ROR = 1.1 ALD2 + 0.96 XO2 + 0.94 HO2 + 0.04 XO2N + 0.02 ROR - 2.10 PAR : ARR2(1.0E+15, -8000.0) ; {54.} ROR = HO2 : 1.6E+3 ; {55.} ROR + NO2 = PROD : 1.5E-11 ; {56.} O + OLE = 0.63 ALD2 + 0.38 HO2 + 0.28 XO2 + 0.3 CO + 0.2 HCHO + 0.02 XO2N + 0.22 PAR + 0.2 OH : ARR2(1.2E-11, -324.0) ; {57.} OH + OLE = HCHO + ALD2 + XO2 + HO2 - PAR : ARR2(5.2E-12, 504.0) ; {58.} O3 + OLE = 0.5 ALD2 + 0.74 HCHO + 0.33 CO + 0.44 HO2 + 0.22 XO2 + 0.1 OH - PAR : ARR2(1.4E-14, -2105.0) ; {59.} NO3 + OLE = 0.91 XO2 + HCHO + ALD2 + 0.09 XO2N + NO2 - PAR : 7.7E-15 ; {60.} O + ETH = HCHO + 0.7 XO2 + CO + 1.7 HO2 + 0.3 OH : ARR2(1.0E-11, -792.0) ; {61.} OH + ETH = XO2 + 1.56 HCHO + HO2 + 0.22 ALD2 : ARR2(2.0E-12, 411.0) ; {62.} O3 + ETH = HCHO + 0.42 CO + 0.12 HO2 : ARR2(1.3E-14, -2633.0) ; {63.} OH + TOL = 0.08 XO2 + 0.36 CRES + 0.44 HO2 + 0.56 TO2 : ARR2(2.1E-12, 322.0) ; {64.} TO2 + NO = 0.9 NO2 + 0.9 OPEN + 0.9 HO2 : 8.1E-12 ; {65.} TO2 = HO2 + CRES : 4.2 ; {66.} OH + CRES = 0.4 CRO + 0.6 XO2 + 0.6 HO2 + 0.3 OPEN : 4.1E-11 ; {67.} NO3 + CRES = CRO + HNO3 : 2.2E-11 ; {68.} CRO + NO2 = PROD : 1.4E-11 ; {69.} OH + XYL = 0.7 HO2 + 0.5 XO2 + 0.2 CRES + 0.8 MGLY + 1.10 PAR + 0.3 TO2 : ARR2(1.7E-11, 116.0) ; {70.} OH + OPEN = XO2 + C2O3 + 2 HO2 + 2 CO + HCHO : 3.0E-11 ; {71.} OPEN + hv = C2O3 + CO + HO2 : 6.0E-3*RCONST(1) ; {72.} O3 + OPEN = 0.03 ALD2 + 0.62 C2O3 + 0.7 HCHO + 0.03 XO2 + 0.69 CO + 0.08 OH + 0.76 HO2 + 0.2 MGLY : ARR2(5.4E-17, -500.0) ; {73.} OH + MGLY = XO2 + C2O3 : 1.7E-11 ; {74.} MGLY + hv = C2O3 + CO + HO2 : 1.86E-2*RCONST(1) ; {75.} O + ISOP = 0.6 HO2 + 0.8 ALD2 + 0.55 OLE + 0.5 XO2 + 0.5 CO + 0.45 ETH + 0.9 PAR : 1.8E-11 ; {76.} OH + ISOP = HCHO + XO2 + 0.67 HO2 + 0.4 MGLY + 0.2 C2O3 + ETH + 0.2 ALD2 + 0.13 XO2N : 9.6E-11 ; {77.} O3 + ISOP = HCHO + 0.4 ALD2 + 0.55 ETH + 0.2 MGLY + 0.06 CO + 0.1 PAR + 0.44 HO2 + 0.1 OH : 1.2E-17 ; {78.} NO3 + ISOP = XO2N : 3.2E-13 ; {79.} XO2 + NO = NO2 : 8.1E-12 ; {80.} 2 XO2 = PROD : ARR2(1.7E-14, 1300.0) ; {81.} XO2N + NO = PROD : 6.8E-13 ; {62/RG71} SO2 + OH = HO2 + PROD : 1.0870e-12 ; {63/RG72} SO2 = PROD : 1.3833e-06 ; {Methane and Methylperoxyl Radical Reactions} {} CH4 + OH = CH3O2 : ARR2(2.4E-12,-1710.0) ; {} CH3O2 + NO = CH3O + NO2 : ARR2(4.15E-12,180.0) ; {} CH3O2 + HO2 = PROD : ARR2(1.7E-13,1000.0) ; {} 2 CH3O2 = 0.76 CH3O + 0.62 HCHO + PROD : ARR2(1.62E-13, 220.0) ; {} CH3O + O2 = HCHO + HO2 : ARR2(7.12E-14,-1080.0); {82/RE21} HO2 = HO2aq : 3.3000e-01 ; {83/RE22} HO2aq = HO2 : 2.2492e+01 ; {84/RE31} H2O2 = H2O2aq : 3.3000e-01 ; {85/RE32} H2O2aq = H2O2 : 6.0790e-01 ; {86/RE41} O3 = O3aq : 1.0500e-02 ; {87/RE42} O3aq = O3 : 1.3012e+05 ; {88/RE51} HCHO = HCHOaq : 2.4000e-01 ; {89/RE52} HCHOaq = HCHO : 5.1931e+00 ; {90/RE61} HCOOH = HCOOHaq : 2.4000e-01 ; {91/RE62} HCOOHaq = HCOOH : 8.8422e+00 ; {92/RE71} ROOH = CH3O2Haq : 2.4000e-01 ; {93/RE72} CH3O2Haq = ROOH : 1.4871e+02 ; {94/RE81} XO2 = CH3O2aq : 2.4000e-01 ; {95/RE82} CH3O2aq = XO2 : 1.6358e+01 ; {96/RE91} HNO3 = HNO3aq : 2.4000e-01 ; {97/RE92} HNO3aq = HNO3 : 1.5579e-01 ; {98/RE101} NO3 = NO3aq : 2.4000e-01 ; {99/RE102} NO3aq = NO3 : 2.1811e+03 ; {100/RE111} NH3 = NH3aq : 2.4000e-01 ; {101/RE112} NH3aq = NH3 : 4.3622e+02 ; {102/RE121} SO2 = SO2aq : 2.4000e-01 ; {103/RE122} SO2aq = SO2 : 2.6599e+04 ; {104/RE131} OH = OHaq : 2.4000e-01 ; {105/RE132} OHaq = OH : 3.6351e+00 ; {106/RE141} N2O5 = HNO3aq + HNO3aq : 7.5000e-02 ; {107/RE151} H2Oaq = HPLUSaq + OHMINaq : 2.3636e-05 ; {108/RE152} HPLUSaq + OHMINaq = H2Oaq : 7.1958e-04 ; {109/RE171} HCOOHaq = HPLUSaq + HCOOMINaq : 8.6000e+06 ; {110/RE172} HPLUSaq + HCOOMINaq = HCOOHaq : 2.6016e-04 ; {111/RE181} HO2aq = HPLUSaq + O2MINaq : 1.6000e+05 ; {112/RE182} HPLUSaq + O2MINaq = HO2aq : 5.5353e-05 ; {113/RE191} SO2aq = HSO3MINaq + HPLUSaq : 3.6000e+06 ; {114/RE192} HSO3MINaq + HPLUSaq = SO2aq : 1.6606e-06 ; {115/RE201} HSO3MINaq = SO32MINaq + HPLUSaq : 1.0000e+04 ; {116/RE202} SO32MINaq + HPLUSaq = HSO3MINaq : 8.3029e-04 ; {117/RE211} NH3aq = NH4aq + OHMINaq : 6.0000e+05 ; {118/RE212} NH4aq + OHMINaq = NH3aq : 1.8820e-04 ; {119/RE221} HNO3aq = NO3MINaq + HPLUSaq : 2.2000e+09 ; {120/RE222} NO3MINaq + HPLUSaq = HNO3aq : 7.7494e-07 ; {121/RW01} FE3PLUSaq = FE2PLUSaq + OHaq : 0.4583E-03 ; {122/RW02} H2O2aq = OHaq + OHaq : 0.7219E-05 ; {123/RW03 } HCHOaq + OHaq = HCOOHaq + HO2aq + H2Oaq : 0.1107E-04 ; {124/RW05} HCOOMINaq + OHaq = O2MINaq + CO2aq : 0.1771E-04 ; {125/RW06} HCOOHaq + OHaq = O2MINaq + HPLUSaq + CO2aq : 0.7196E-06 ; {126/RW07} HSO3MINaq + OHaq = SO42MINaq + HPLUSaq : 0.2491E-04 ; {127/RW08} HMSAaq + OHaq = SO42MINaq + HCHOaq + HPLUSaq : 0.5535E-05 ; {128/RW09} FE2PLUSaq + OHaq = FE3PLUSaq + OHMINaq: 0.2380E-05 ; {129/RW10} H2O2aq + OHaq = H2Oaq + HO2aq : 0.1495E-06 ; {130/RW11} O3aq + OHaq = HO2aq : 0.1661E-04 ; {131/RW13} O2MINaq + FE2PLUSaq = FE3PLUSaq + H2O2aq + OHMINaq + OHMINaq : 0.5535E-07 ; {132/RW14} O2MINaq + FE3PLUSaq = FE2PLUSaq : 0.8303E-06 ; {133/RW15} O2MINaq + CUPLUSaq = CU2PLUSaq + H2O2aq + OHMINaq + OHMINaq : 0.4982E-04 ; {134/RW16} O2MINaq + CU2PLUSaq = CUPLUSaq : 0.4428E-04 ; {135/RW17} O2MINaq + O3aq = OHaq + OHMINaq : 0.8303E-05 ; {136/RW18} HO2aq + FE2PLUSaq = FE3PLUSaq + H2O2aq + OHMINaq : 0.6642E-08 ; {137/RW19} HO2aq + FE3PLUSaq = FE2PLUSaq + HPLUSaq : 0.5535E-10 ; {138/RW20} HO2aq + CUPLUSaq = CU2PLUSaq + H2O2aq + OHMINaq : 0.5535E-05 ; {139/RW21} HO2aq + CU2PLUSaq = CUPLUSaq + HPLUSaq : 0.2768E-06 ; {140/RW22} H2O2aq + HSO3MINaq = SO42MINaq + H2Oaq + HPLUSaq : 0.5535E-14 ; {141/RW23} H2O2aq + FE2PLUSaq = FE3PLUSaq + OHaq + OHMINaq : 0.5535E-14 ; {142/RW24} H2O2aq + CUPLUSaq = CU2PLUSaq + OHaq + OHMINaq : 0.2214E-08 ; {143/RW25} CUPLUSaq = CU2PLUSaq + O2MINaq : 0.2500E-03 ; {144/RW26} CUPLUSaq + FE3PLUSaq = CU2PLUSaq + FE2PLUSaq : 0.1661E-06 ; {145/RW27} CUPLUSaq + O3aq = CU2PLUSaq + OHaq + OHMINaq : 0.5535E-07 ; {146/RW28} FE2PLUSaq + O3aq = FE3PLUSaq + OHaq + OHMINaq : 0.4539E-08 ; {147/RW29} FE3PLUSaq + HSO3MINaq = FE2PLUSaq + SO42MINaq + HPLUSaq : 0.5535E-14 ; {148/RW30} O3aq + HSO3MINaq = SO42MINaq + HPLUSaq : 0.1716E-08 ; {149/RW31} O3aq + SO32MINaq = SO42MINaq : 0.5535E-05 ; {150/RW32} O3aq = H2O2aq : 0.2355E-04 ; {151/RW34} HO2aq + O2MINaq = H2O2aq + OHMINaq : 0.5535E-06 ; {152/RW35} HO2aq + HO2aq = H2O2aq : 0.4594E-08 ; {153/RW39} SO32MINaq + HCHOaq = HMSAaq + OHMINaq : 0.1384E-06 ; {154/RW40} HMSAaq + OHMINaq = SO32MINaq + HCHOaq : 0.1993E-10 ; {155/RW42} CH3O2aq + O2MINaq = CH3O2Haq + OHMINaq : 0.2768E-06 ; {156/RW43} CH3O2Haq + OHaq = CH3O2aq + H2Oaq : 0.1495E-06 ; {157/RW44} CH3O2Haq + OHaq = HCHOaq + OHaq : 0.1052E-06 ; {CO2 reactions} CO2aq = HPLUSaq + HCO3MINaq : 1.0E-4 ; HPLUSaq + HCO3MINaq = CO2aq : 1.2178E-12 ; {CO2aq + H2Oaq = H2CO3aq : 0*3.0E-2 ; H2CO3aq = CO2aq + H2Oaq : 0*1.19E+1 ; H2CO3aq = HPLUSaq + HCO3MINaq : 0*8.0E+6 ; HPLUSaq + HCO3MINaq = H2CO3aq : 0*4.7E+10 ; HPLUSaq + HCO3MINaq = CO2aq : 0*1.5E+4 ; CO2aq + H2Oaq = HPLUSaq + HCO3MINaq : 0*1.0E-2 ;}