!> @file chem_photolysis_mod.f90 !------------------------------------------------------------------------------! ! This file is part of the PALM model system. ! ! PALM is free software: you can redistribute it and/or modify it under the ! terms of the GNU General Public License as published by the Free Software ! Foundation, either version 3 of the License, or (at your option) any later ! version. ! ! PALM is distributed in the hope that it will be useful, but WITHOUT ANY ! WARRANTY; without even the implied warranty of MERCHANTABILITY or FITNESS FOR ! A PARTICULAR PURPOSE. See the GNU General Public License for more details. ! ! You should have received a copy of the GNU General Public License along with ! PALM. If not, see . ! ! Copyright 1997-2017 Leibniz Universitaet Hannover ! Copyright 2017-2017 Karlsruhe Institute of Technology !------------------------------------------------------------------------------! ! ! Current revisions: ! ----------------- ! ! ! Former revisions: ! ----------------- ! $Id: chem_photolysis_mod.f90 2696 2017-12-14 17:12:51Z kanani $ ! Initial revision ! ! ! ! ! Authors: ! -------- ! @author Renate Forkel ! ! !------------------------------------------------------------------------------! ! Description: ! ------------ !> photolysis models and interfaces (Adapted from photolysis_model_mod.f90) !> @todo Alles! !------------------------------------------------------------------------------! MODULE chem_photolysis_mod #if defined( __chem ) USE arrays_3d, & ONLY: dzw, hyp, pt, q, ql, zu, zw USE constants, & ONLY: pi USE control_parameters, & ONLY: time_since_reference_point USE pegrid, ONLY: myid, threads_per_task USE indices, & ONLY: nxl, nxlg, nxr, nxrg, nyn, nyng, nys, nysg, nzb, nzt USE radiation_model_mod, & ONLY: calc_zenith, zenith !day, day_init, lat, lambda, lon, & !time_utc, time_utc_init, !FKa: This is now handled by date_and_time_mod USE control_parameters, & ONLY: initializing_actions ! ONLY: cloud_droplets, cloud_physics, g, initializing_actions, & ! large_scale_forcing, lsf_surf, phi, pt_surface, rho_surface, & ! surface_pressure, time_since_reference_point USE chem_gasphase_mod, & ONLY: nphot, phot_names, phot USE chemistry_model_mod, & ONLY: phot_frequen, photolysis_scheme USE chem_modules, & ONLY: chem_debug2 ! REAL(wp), DIMENSION(0:0) :: zenith, & !< cosine of solar zenith angle ! sun_dir_lat, & !< solar directional vector in latitudes ! sun_dir_lon !< solar directional vector in longitudes USE kinds #if defined ( __netcdf ) USE NETCDF #endif IMPLICIT NONE ! LOGICAL :: unscheduled_photolysis_calls = .TRUE., & !< flag parameter indicating whether additional calls of the photolysis code are allowed ! constant_albedo = .FALSE., & !< flag parameter indicating whether the albedo may change depending on zenith ! force_photolysis_call = .FALSE., & !< flag parameter for unscheduled photolysis calls ! photolysis = .FALSE., & !< flag parameter indicating whether the photolysis model is used ! sun_up = .TRUE., & !< flag parameter indicating whether the sun is up or down ! photolysis = .TRUE., & !< flag parameter indicing whether photolysis shall be calculated ! sun_direction = .FALSE. !< flag parameter indicing whether solar direction shall be calculated !-- Parameters for constant photolysis frequencies INTEGER,PARAMETER :: nconst = 15 !< available predefined photolysis prequencies for constant ! Names for predefined fixed photolysis frequencies at zenith angle 0 CHARACTER(LEN=10), PARAMETER, DIMENSION(nconst) :: names_c = (/ & 'J_O31D ','J_O33P ','J_NO2 ','J_HNO3 ','J_RCHO ', & 'J ','J ','J ','J ','J ', & 'J ','J ','J ','J ','J ' /) ! Photolysis frequency at zenith angle 0 in 1/s REAL(wp), PARAMETER, DIMENSION(nconst) :: phot0 = (/ & 2.489E-05_wp,3.556E-04_wp, 8.89E-03_wp,5.334E-07_wp,3.734E-05_wp, & 0.0000E00_wp,0.0000E00_wp,0.0000E00_wp,0.0000E00_wp,0.0000E00_wp, & 0.0000E00_wp,0.0000E00_wp,0.0000E00_wp,0.0000E00_wp,0.0000E00_wp /) !-- Parameters for simple photolysis frequencies INTEGER,PARAMETER :: nsimple = 15 !< available predefined photolysis prequencies for simpel parameterisation ! Names for simple photolysis frequencies parameterisation ( CHARACTER(LEN=10), PARAMETER, DIMENSION(nsimple) :: names_s = (/ & 'J_O31D ','J_O33P ','J_H2O2 ','J_NO2 ','J_NO3_A ', & 'J_NO3_B ','J_HONO ','J_HNO3 ','J_HCHO_A ','J_HCHO_B ', & 'J_CH3CHO ','J ','J ','J ','J_RCHO ' /) !-- Parameters for simeple photolysis frequencies from MCM (http://mcm.leeds.ac.uk/MCM) !-- Saunders et al., 2003, Atmos. Chem. Phys., 3, 161-180 REAL(wp), PARAMETER, DIMENSION(nconst) :: par_l = (/ & 6.073E-05_wp,4.775E-04_wp,1.041E-05_wp,1.165E-02_wp,2.485E-02_wp, & 1.747E-01_wp,2.644E-03_wp,9.312E-07_wp,4.642E-05_wp,6.853E-05_wp, & 7.344E-06_wp,0.0000E00_wp,0.0000E00_wp,0.000E00_wp, 6.853E-05_wp /) REAL(wp), PARAMETER, DIMENSION(nconst) :: par_m = (/ & 1.743_wp, 0.298_wp, 0.723_wp, 0.244_wp, 0.168_wp, & 0.155_wp, 0.261_wp, 1.230_wp, 0.762_wp, 0.477_wp, & 1.202_wp, 0.000_wp, 0.000_wp, 0.000_wp, 0.477_wp /) REAL(wp), PARAMETER, DIMENSION(nconst) :: par_n = (/ & 0.474_wp, 0.080_wp, 0.279_wp, 0.267_wp, 0.108_wp, & 0.125_wp, 0.288_wp, 0.307_wp, 0.353_wp, 0.323_wp, & 0.417_wp, 0.000_wp, 0.000_wp, 0.000_wp, 0.323_wp /) REAL(wp) :: time_photolysis = 0.0_wp, & !< time since last call of photolysis code dt_photolysis = 0.0_wp, & !< hotolysis model timestep skip_time_do_photolysis = 0.0_wp !< Radiation model is not called before this time REAL(wp) :: cosz = 0.7_wp !< cosine of Zenith angle (45 deg, if not specified otherwise) ! !-- Variables and parameters used in Fast-J only ! .... ! INTERFACE photolysis_check_parameters ! MODULE PROCEDURE photolysis_check_parameters ! END INTERFACE photolysis_check_parameters INTERFACE photolysis_constant MODULE PROCEDURE photolysis_constant END INTERFACE photolysis_constant INTERFACE photolysis_simple MODULE PROCEDURE photolysis_simple END INTERFACE photolysis_simple ! ! INTERFACE photolysis_fastj ! MODULE PROCEDURE photolysis_fastj ! END INTERFACE photolysis_fastj ! INTERFACE photolysis_control MODULE PROCEDURE photolysis_control END INTERFACE photolysis_control ! INTERFACE photolysis_header ! MODULE PROCEDURE photolysis_header ! END INTERFACE photolysis_header ! INTERFACE photolysis_init MODULE PROCEDURE photolysis_init END INTERFACE photolysis_init ! INTERFACE photolysis_parin ! MODULE PROCEDURE photolysis_parin ! END INTERFACE photolysis_parin ! INTERFACE photolysis_read_restart_data ! MODULE PROCEDURE photolysis_read_restart_data ! END INTERFACE photolysis_read_restart_data ! INTERFACE photolysis_last_actions ! MODULE PROCEDURE photolysis_last_actions ! END INTERFACE photolysis_last_actions SAVE PRIVATE ! !-- Public functions / NEEDS SORTING ! PUBLIC photolysis_init ! photolysis_check_parameters, photolysis_control, & ! photolysis_header, photolysis_init, photolysis_parin !, & ! photolysis_define_netcdf_grid, photolysis_last_actions, & ! photolysis_read_restart_data, photolysis_data_output_mask PUBLIC photolysis_control, photolysis_init PUBLIC photolysis_scheme ! CONTAINS !------------------------------------------------------------------------------! ! Description: ! ------------ !> This subroutine controls the calls of the photolysis schemes !------------------------------------------------------------------------------! SUBROUTINE photolysis_control IMPLICIT NONE SELECT CASE ( TRIM( photolysis_scheme ) ) CASE ( 'constant' ) CALL photolysis_constant CASE ( 'simple' ) CALL photolysis_simple ! CASE ( 'fastj' ) ! CALL photolysis_fastj CASE DEFAULT END SELECT END SUBROUTINE photolysis_control !------------------------------------------------------------------------------! ! Description: ! ------------ !> Initialization of the photolysis model !------------------------------------------------------------------------------! SUBROUTINE photolysis_init !### not yes used. Call should be placed near call of chem_init IMPLICIT NONE !-- Just in case we need anything RETURN END SUBROUTINE photolysis_init !------------------------------------------------------------------------------! ! Description: ! ------------ !> This scheme keeps the prescribed net radiation constant during the run !> Default zenith angle is 45 deg !------------------------------------------------------------------------------! SUBROUTINE photolysis_constant IMPLICIT NONE ! INTEGER(iwp) :: i, j, k !< loop indices INTEGER(iwp) :: iphot,iav !< loop indix for photolysis reaction ! REAL(wp) :: exn, & !< Exner functions at surface ! pt1 !< potential temperature at first grid level DO iphot = 1,nphot DO iav = 1,nconst IF ( TRIM( names_c(iav) ) == TRIM( phot_names(iphot) ) ) then !-- Prescribe fixed photolysis frequencies [1/s] ! IF(myid == 0 .AND. chem_debug2 ) WRITE(06,*) iphot, iav,phot_names(iphot),names_c(iav) phot_frequen(iphot)%freq(nzb+1:nzt,:,:) = & phot0(iav) * cosz ! IF(myid == 0 .AND. chem_debug2 ) WRITE(06,*) phot_frequen(iphot)%freq(1,5,5) ENDIF ENDDO ENDDO END SUBROUTINE photolysis_constant !------------------------------------------------------------------------------! ! Description: ! ------------ !> This scheme applies a simple parameterisation for clear sky photolysis frequencies !> from the Master Chemical Mechanism, MCM v3.2 (http://mcm.leeds.ac.uk/MCM). !> Reference: Saunders et al., Atmos. Chem. Phys., 3, 161, 2003 !------------------------------------------------------------------------------! SUBROUTINE photolysis_simple IMPLICIT NONE ! INTEGER(iwp) :: i, j, k !< loop indices INTEGER(iwp) :: iphot,iav !< loop indix for photolysis reaction ! REAL(wp) :: exn, & !< Exner functions at surface ! pt1 !< potential temperature at first grid level REAL(wp) :: coszi !< 1./cosine of zenith angle DO iphot = 1,nphot phot_frequen(iphot)%freq = 0.0_wp ENDDO CALL calc_zenith IF ( zenith(0) > 0.0_wp ) THEN coszi = 1. / zenith(0) DO iphot = 1,nphot DO iav = 1,nsimple IF ( TRIM( names_s(iav) ) == TRIM( phot_names(iphot) ) ) then ! if(myid == 0 .AND. chem_debug2 ) WRITE(06,*) 'simple', iphot, iav,phot_names(iphot),names_s(iav) phot_frequen(iphot)%freq(nzb+1:nzt,:,:) = & par_l(iav) * zenith(0)**par_m(iav) * EXP( -par_n(iav) * coszi ) ! if(myid == 0 .AND. chem_debug2 ) WRITE(06,*) 'simple', phot_frequen(iphot)%freq(1,5,5) ENDIF ENDDO ENDDO ENDIF END SUBROUTINE photolysis_simple #endif END MODULE chem_photolysis_mod